Sunday, 2 November 2014

The decreasing of the fossil fuels and the deteriorating of environment has pushed forward study on the utilization of hydrogen as the alternative fuel. Although the first attempt was reported by Reverend W. Cecil as early as 1817, the development of the hydrogen engine began in the 1930s, and was built to a crescendo in 1970s. In the 1930s there were 1000 vehicles which run with the hydrogen in America and German, and the hydrogen engine was used by the former Soviet Union during the Great Patriotic War. It has been proven that the regular vehicle body structure is suitable for hydrogen power system while the standard gasoline engines can be easily converted to hydrogen ICE.
It was not until the 1990s that the researches in the hydrogen engine were again rekindled. Mazda, who has made irreplaceable contributions in the hydrogen rotary engine field, introduced their first prototype, Mazda HR-X, which was using a hydrogen Wankel engine in the year 1991. The Mazda5, which is the second generation of the Mazda Premacy, was offered by Mazda in 2005. In the same year, BMW was focusing their attention on the research of the BMW Hydrogen 7 and BMW H2R, both of which were using a liquid hydrogen internal combustion engine while a Tri-Flex engine pickup, F-250 Super Chief was introduced by Ford.

The prosperity of hydrogen engine cannot go without the hydrogen production and storage. Gas, coal and biomass energy are the main source of hydrogen. Hydrogen can also be recycled during the process of chlor-alkali industry, metallurgical industry, etc. Currently, more economical methods to obtain hydrogen (e.g. Steam Reforming of Methane, exhaust-gas purification, SPEWE) have been developed and optimized the hydrogen production. However, the hydrogen storage is more urgent to be solved compared with the hydrogen production. For automotive applications, the methods will be discussed in this paper.

Advantages of H2 as a fuel
Hydrogen has superior properties which gives significant advantages compared with other types of fuel.
l  Wide range of flammability
l  High flame speed
l  Small quenching distance
l  High auto ignition temperature and low ignition energy
l  High diffusivity
Hydrogen engine has a better performance at high speed operation compared to gasoline engine. Besides, the emission of CO and HC, which is determined by the air-fuel ratio, is less than gasoline operation. Due to the combustion properties of hydrogen, shorter time for combustion produces lower end gas temperature, thus increases the operating range of the utilisation of hydrogen.
However the emission of NOx is, in some cases, even more than gasoline operation. NOx is the general term of NO, NO2, N2O3, N2O4 and N2O5. The main part of NOx, which is NO, can be oxidized to NO2, a toxic gas with an offensive smell, by the Ozone in the atmosphere.

BMW Hydrogen 7

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